Just move the first row outside the scrolling div into a div and table of its own. To get things to line up, adjust the css on the new div and on the new td's a little as shown, and you're good to go:
Code:
<div style='width:725px;background-color:#DFE9BF;line-height:19px;border:solid 1px #000;border-bottom-width:0;margin:auto;'>
<table style="font-family: 'sans-serif',Helvetica, Arial, sans-serif;">
<tr style='background-color:#EFF9CF;'>
<td style='width:90px;'><b>Date</b></td>
<td style='width:217px;'><b>Title</b></td>
<td style='width:213px;'><b>Verse</b></td>
<td style='width:205px;'><b>Preacher</b></td>
</tr>
</table>
</div>
<div style='height:375px;overflow:auto;scrollbar-base-color:tan;width:725px;background-color:#DFE9BF;line-height:19px;border:solid 1px #000;border-top-width:0;;margin:auto;'>
<table style="font-family: 'sans-serif',Helvetica, Arial, sans-serif;">
<tr class='a1hover'>
<td style='width:90px;'><a href="http://www.sovgraceopc.org/audio/120411.mp3">2011-12-4</a></td>
<td style='width:220px;'>A Tale of Two Annunciations</td>
<td style='width:220px;'>Luke 1:26-38</td>
<td style='width:195px;'>Ken Golden</td>
</tr><tr class='a1hover'>
<td><a href="http://www.sovgraceopc.org/audio/112711a.mp3">2011-11-27</a></td>
<td>The Lord Remembered</td>
<td>Luke 1:5-25</td>
<td>Ken Golden</td>
</tr><tr class='a1hover'>
<td><a href="http://www.sovgraceopc.org/a . . .
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