I'm guessing (because I couldn't test it) that adding text-align: center; for class="c5" <span> and class="c6" <TD> style rules might fix this. The clickflame image in <TD c6> is an inline element that would be treated like a text character, and the background image is centered. You probably could combine and eliminate some of the multitude of overly specific style rules.
Code:
<style type="text/css">
div.c9 {clear:both}
p.c8 {text-align:center}
em.c7 {text-decoration: underline}
td.c6 {background-image: url(images/rec3.jpg); background-repeat: no-repeat; background-position: center center}
span.c5 {color: #FF0000; font-size:150%;}
p.c4 {text-align:center;}
div.c3 {text-align: center;}
h2.c2 {text-align:center;}
div.c1 {text-align:center;}
</style>
<td style="width:33%" class="c6">
<a href="javascript:popUp('media/convention/empower.html')">
<img src="images/clickflame.gif" border="0" height="45" width="170" alt="click flame"></a>
<br>
<strong><em><span class="c5">To watch the video</span></em></strong>
</td>
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