Conditional comments can only be used to target IE. What you could do is to target all other browsers like so:
Code:
<!--[if IE]><link href="styles.css" rel="stylesheet" type="text/css"><![endif]-->
<!--[if !IE]><link href="styles2.css" rel="stylesheet" type="text/css"><![endif]-->
Or just use the fact that the styles are cascading and change the order. In this way, all browsers will use the first one, but only IE will be able to use the second one, which will replace the first one, assuming that the same elements are targeted:
Code:
<link href="styles2.css" rel="stylesheet" type="text/css">
<!--[if IE]><link href="styles.css" rel="stylesheet" type="text/css"><![endif]-->
Good luck!
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