If you don't know much about cross browser HTML coding, Dreamweaver is actually pretty good at it so you could just use its design features and skip 'show code view'.
However, your layout doesn't seem too far off, so you could use one stylesheet for IE and another for all other browsers.
Have the main stylesheet first on the page and make things look good in FF and/or Opera with it. Follow it with something like:
Code:
<!--[if IE]>
<link rel="stylesheet" type="text/css" href="css/ie_styles.css" media="screen" title="default">
<![endif]-->
You only need to include the styles in there that need to be different for IE.
Also, you would be better of designing in HTML strict or transitional. XHTML can throw some browsers into quirks mode so, isn't that good of a DOCTYPE for normal HTML pages.
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